DOI https://doi.org/10.36487/ACG_repo/963_2
		  
		  
		  
		  Cite As:
		  de Araujo, AC, Valadão, GES & Falcucci, A 2009, 'Factorial Design 2n in Bauxite Tailings Flocculation and Bingham Model for Rheological Characteristics', in R Jewell, AB Fourie, S Barrera & J Wiertz (eds), 
Paste 2009: Proceedings of the Twelfth International Seminar on Paste and Thickened Tailings, Australian Centre for Geomechanics, Perth, pp. 11-20, 
https://doi.org/10.36487/ACG_repo/963_2	
		  	
		  
		  
		  
		  
    
          
		  
		  
		  Abstract:
		  
		  
		  
		  In the last years, the disposal of tailings in the form of pastes and/or high-density slurries has gained 
importance as it may present significant advantages in comparison to more traditional disposal techniques. 
The knowledge of physical chemical characteristics of the material to be disposed, as well as the interactions 
that result from the use of polymeric flocculants on solid/liquid separation can lead to the formation of 
pastes and/or high-density slurries with adequate conditions for handling and final disposal.  
With the help of factorial design tool (2²), with pH and flocculant dosage as independent variables, the 
effects of three different polyacrylamide flocculants was evaluated on the final per cent solids of a bauxite 
tailings flocculated material, over a pH range from 5 to 7 and different dosages of flocculants. These factors 
were analysed by fitting the experimental data to a polynomial model, which plots settling rates response in 
the form of contour maps. 
Regarding the final percentage of solids of the flocculated material, a cationic polymer presented the best 
results among the three flocculants tested. With a dosage of 130 g/t and pH 5, the final percentage of solids 
(by wt.) was 31.2% after one hour. 
The rheological characteristics for different percentage of solids are determined with the help of the 
Bingham model, where the viscosity and yield stress of a bauxite tailing are available without a presence of 
flocculant. 
According to the utilised model, the yield stress show a signification increase for to the slurry with  
25–30 per cent of solid by weight, with a viscosity of between 8.2 and 13.0 cP and a yield stress between 3.0 
and 6.8 Pa. 
		  
		  
		  
		  
		  
		  
		  
		  
References:
		  	
			  Barnes, H.A., Hutton, J.F. and Walters, K. (1989) An introduction to rheology, 1st ed. New York: Elsevier, Rheology
		  	
			  Series 3, 199 p.
		  	
			  Boger, D.V. and Nguyen, Q.D. (1998) Application rheology to solving tailings disposal problems, International Journal
		  	
			  of Mineral Processing, Vol. 54, pp. 217–233.
		  	
			  Box, G.E.P., Hunter, W.G. and Hunter, J.S. (1978) Statistics for experimenters, Wiley, New York.
		  	
			  Derjaguin, B. and Landau L. (1941) Theory of the stability of strongly charged lyophobic sols and of the adhesion of
		  	
			  strongly charged particles in solutions of electrolytes, Acta Physico chemica URSS 14:633.
		  	
			  Falcucci, A. (2007) A influência de floculantes poliméricos na formação de pastas minerais, M.Sc. Thesis in Mineral
		  	
			  Processing Technology, Mining Engineering Department – UFMG, Brazil.
		  	
			  Farinato, R.S., Ravishakar, S.A. and Chen, H.T. (2003) Rational polymer design for solid-liquid separations in mineral
		  	
			  processing applications, International Journal of Mineral Processing, Vol. 72, pp. 75–86.
		  	
			  Ferreira, E.E., Brandão, P.R.G., Klein, B. and Peres, A.E.C. (2005) Reologia de suspensões minerais: Uma revisão,
		  	
			  REM: Revista da Escola de Minas, Ouro Preto, Vol. 58(1), pp. 83–87.
		  	
			  Fitch, B. (1966) Current theory and thickener design, Ind. Eng. Chem., Vol. 58(10), pp. 18–28.
		  	
			  Fuerstenau, D.W. and Pradip. (2005) Zeta potentials in the flotation of oxide and silicate minerals, Advances in Colloid
		  	
			  and Interface Science, Vol. 114–115, pp. 9–26.
		  	
			  Hogg, R. (2004) Flocculation by polymers: Mechanisms, dynamics and process design. Journal of Ore Dressing, Vol. 6,
		  	
			  
		  	
			  Johnson, S.B., Franks, G.V., Scales, P.J., Boger, D.V. and Healy, T.W. (2000) Surface chemistry-rheology relationships
		  	
			  in concentrated mineral suspensions, International Journal of Mineral Processing, Vol. 58, pp. 267–304.
		  	
			  Kwak, M., James, D.F. and Klein, K.A. (2005) Flow behaviour of tailings paste for surface disposal, International
		  	
			  Journal of Mineral Processing, in press.
		  	
			  Litzenberger, C.G. (2003) Rheological study of kaolin clay slurry, M.Sc. Thesis in Chemical Engineering, University of
		  	
			  Saskatchewan, Saskatoon, SK.
		  	
			  Mular, A.L. and Roberts, R.B. (1966) A simplified method to determine isoelectric points of oxides, Transactions of the
		  	
			  Canadian Institute of Mining and Metallurgy, Canada, pp. 438–439.
		  	
			  Pearse, M.J. (2005) An overview of the use of chemical reagents in mineral processing, Minerals Engineering, Vol. 18,
		  	
			  pp. 139–149.
		  	
			  Ralston, J., Jenkins, P. and Huynh, L. (2000) Modification of the rheological properties of concentrated slurries by
		  	
			  control of mineral-solution interfacial chemistry, International Journal of Mineral Processing, Vol. 59,
		  	
			  pp. 305–325.
		  	
			  Sheridan, M.S., Nagaraj, D.R., Fornasiero, D. and Ralston, J. (2002) The use of factorial experimental design to study
		  	
			  collector properties of N-allyl-O-alkyl thiocarbamate collector in the flotation of a cooper ore, Minerals
		  	
			  Engineering, Vol. 15, pp. 333–340.
		  	
			  Verwey, E.J.W. and Overbeek, J.Th.G. (1948) Theory of the stability of lyophobic colloids, Elsevier, Amsterdam.
		  	
			  20 Paste 2009, Viña del Mar, Chile